TY - JOUR
T1 - Gas‐Phase Reactions of M+ and [CpM]+ (M = Fe, Co, Ni) with 1,3,5‐Trisilacyclohexane
T2 - First Evidence for the Formation of 1,3,5‐Trisilabenzene
AU - Bjarnason, Asgeir
AU - Arnason, Ingvar
PY - 1992/12
Y1 - 1992/12
N2 - Preferential elimination of HD in the gasphase reactions of [CpM]+, M = Fe, Co, Ni, with deuterated trisilacyclohexane 1 points to the formation of trisilabenzene, previously unknown, as a ligand. The results of collision experiments also support the formation of 2 (deuterated) in these reactions. (Figure Presented.)
AB - Preferential elimination of HD in the gasphase reactions of [CpM]+, M = Fe, Co, Ni, with deuterated trisilacyclohexane 1 points to the formation of trisilabenzene, previously unknown, as a ligand. The results of collision experiments also support the formation of 2 (deuterated) in these reactions. (Figure Presented.)
UR - https://www.scopus.com/pages/publications/33748216770
U2 - 10.1002/anie.199216331
DO - 10.1002/anie.199216331
M3 - Article
SN - 0570-0833
VL - 31
SP - 1633
EP - 1634
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 12
ER -