Temperature and dose dependence of defect complex formation with ion implanted Mn/Fe in ZnO

T. E. Mølholt; R. Mantovan; H. P. Gunnlaugsson; K. Bharuth-Ram; M. Fanciulli; H. P. Gíslason; K. Johnston; Y. Kobayashi; G. Langouche; H. Masenda; D. Naidoo; S. Ólafsson; R. Sielemann; G. Weyer

doi:10.1016/j.physb.2009.08.187

Temperature and dose dependence of defect complex formation with ion implanted Mn/Fe in ZnO

T. E. Mølholt, R. Mantovan, H. P. Gunnlaugsson, K. Bharuth-Ram, M. Fanciulli, H. P. Gíslason, K. Johnston, Y. Kobayashi, G. Langouche, H. Masenda, D. Naidoo, S. Ólafsson, R. Sielemann, G. Weyer

University of Iceland

Research output: Contribution to journal › Article › peer-review

Abstract

⁵⁷Fe Mössbauer spectroscopy following ion implantation of radioactive ⁵⁷Mn⁺ ( T_1/2=85.4 s) has been applied to study the formation of Fe/Mn implantation-induced defects in ZnO at temperatures between 319 and 390 K. The formation of ferric iron-vacancy complexes is found to depend strongly on the implanted dose and to be faster and more efficient at higher temperatures. The results at these temperatures suggest the mobility of the Zn vacancy, together with vacancy trapping at the substitutional Mn/Fe impurities are responsible for the formation of Fe-V_Zn complexes.

Original language	English
Pages (from-to)	4820-4822
Number of pages	3
Journal	Physica B: Condensed Matter
Volume	404
Issue number	23-24
DOIs	https://doi.org/10.1016/j.physb.2009.08.187
Publication status	Published - 15 Dec 2009

Bibliographical note

Funding Information: This work was supported by the European Union Sixth Framework through RII3-EURONS. K. Bharuth-Ram, H. Masenda and D. Naidoo acknowledge support from the South African National Research Foundations. T.E. Mølholt acknowledges support from the Icelandic Research Fund.

Other keywords

Defect complexes
Mn and Fe ion implantation
Mössbauer spectroscopy
ZnO

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10.1016/j.physb.2009.08.187

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Mølholt, T. E., Mantovan, R., Gunnlaugsson, H. P., Bharuth-Ram, K., Fanciulli, M., Gíslason, H. P., Johnston, K., Kobayashi, Y., Langouche, G., Masenda, H., Naidoo, D., Ólafsson, S., Sielemann, R., & Weyer, G. (2009). Temperature and dose dependence of defect complex formation with ion implanted Mn/Fe in ZnO. Physica B: Condensed Matter, 404(23-24), 4820-4822. https://doi.org/10.1016/j.physb.2009.08.187

@article{a01265a8ad244af1871219f264527def,

title = "Temperature and dose dependence of defect complex formation with ion implanted Mn/Fe in ZnO",

abstract = "57Fe M{\"o}ssbauer spectroscopy following ion implantation of radioactive 57Mn+ ( T1/2=85.4 s) has been applied to study the formation of Fe/Mn implantation-induced defects in ZnO at temperatures between 319 and 390 K. The formation of ferric iron-vacancy complexes is found to depend strongly on the implanted dose and to be faster and more efficient at higher temperatures. The results at these temperatures suggest the mobility of the Zn vacancy, together with vacancy trapping at the substitutional Mn/Fe impurities are responsible for the formation of Fe-VZn complexes.",

keywords = "Defect complexes, Mn and Fe ion implantation, M{\"o}ssbauer spectroscopy, ZnO",

author = "M{\o}lholt, \{T. E.\} and R. Mantovan and Gunnlaugsson, \{H. P.\} and K. Bharuth-Ram and M. Fanciulli and G{\'i}slason, \{H. P.\} and K. Johnston and Y. Kobayashi and G. Langouche and H. Masenda and D. Naidoo and S. {\'O}lafsson and R. Sielemann and G. Weyer",

note = "Funding Information: This work was supported by the European Union Sixth Framework through RII3-EURONS. K. Bharuth-Ram, H. Masenda and D. Naidoo acknowledge support from the South African National Research Foundations. T.E. M{\o}lholt acknowledges support from the Icelandic Research Fund.",

year = "2009",

month = dec,

day = "15",

doi = "10.1016/j.physb.2009.08.187",

language = "English",

volume = "404",

pages = "4820--4822",

journal = "Physica B: Condensed Matter",

issn = "0921-4526",

publisher = "Elsevier B.V.",

number = "23-24",

}

Mølholt, TE, Mantovan, R, Gunnlaugsson, HP, Bharuth-Ram, K, Fanciulli, M, Gíslason, HP, Johnston, K, Kobayashi, Y, Langouche, G, Masenda, H, Naidoo, D, Ólafsson, S, Sielemann, R & Weyer, G 2009, 'Temperature and dose dependence of defect complex formation with ion implanted Mn/Fe in ZnO', Physica B: Condensed Matter, vol. 404, no. 23-24, pp. 4820-4822. https://doi.org/10.1016/j.physb.2009.08.187

TY - JOUR

T1 - Temperature and dose dependence of defect complex formation with ion implanted Mn/Fe in ZnO

AU - Mølholt, T. E.

AU - Mantovan, R.

AU - Gunnlaugsson, H. P.

AU - Bharuth-Ram, K.

AU - Fanciulli, M.

AU - Gíslason, H. P.

AU - Johnston, K.

AU - Kobayashi, Y.

AU - Langouche, G.

AU - Masenda, H.

AU - Naidoo, D.

AU - Ólafsson, S.

AU - Sielemann, R.

AU - Weyer, G.

N1 - Funding Information: This work was supported by the European Union Sixth Framework through RII3-EURONS. K. Bharuth-Ram, H. Masenda and D. Naidoo acknowledge support from the South African National Research Foundations. T.E. Mølholt acknowledges support from the Icelandic Research Fund.

PY - 2009/12/15

Y1 - 2009/12/15

N2 - 57Fe Mössbauer spectroscopy following ion implantation of radioactive 57Mn+ ( T1/2=85.4 s) has been applied to study the formation of Fe/Mn implantation-induced defects in ZnO at temperatures between 319 and 390 K. The formation of ferric iron-vacancy complexes is found to depend strongly on the implanted dose and to be faster and more efficient at higher temperatures. The results at these temperatures suggest the mobility of the Zn vacancy, together with vacancy trapping at the substitutional Mn/Fe impurities are responsible for the formation of Fe-VZn complexes.

AB - 57Fe Mössbauer spectroscopy following ion implantation of radioactive 57Mn+ ( T1/2=85.4 s) has been applied to study the formation of Fe/Mn implantation-induced defects in ZnO at temperatures between 319 and 390 K. The formation of ferric iron-vacancy complexes is found to depend strongly on the implanted dose and to be faster and more efficient at higher temperatures. The results at these temperatures suggest the mobility of the Zn vacancy, together with vacancy trapping at the substitutional Mn/Fe impurities are responsible for the formation of Fe-VZn complexes.

KW - Defect complexes

KW - Mn and Fe ion implantation

KW - Mössbauer spectroscopy

KW - ZnO

UR - https://www.scopus.com/pages/publications/74349110493

U2 - 10.1016/j.physb.2009.08.187

DO - 10.1016/j.physb.2009.08.187

M3 - Article

SN - 0921-4526

VL - 404

SP - 4820

EP - 4822

JO - Physica B: Condensed Matter

JF - Physica B: Condensed Matter

IS - 23-24

ER -

Temperature and dose dependence of defect complex formation with ion implanted Mn/Fe in ZnO

Abstract

Bibliographical note

Other keywords

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