The role of dissociative electron attachment in focused electron beam induced processing: A case study on cobalt tricarbonyl nitrosyl

Sarah Engmann; Michal Stano; Štefan Matejčík; Oddur Ingólfsson

doi:10.1002/anie.201103234

The role of dissociative electron attachment in focused electron beam induced processing: A case study on cobalt tricarbonyl nitrosyl

Sarah Engmann
, Michal Stano
, Štefan Matejčík
, Oddur Ingólfsson

Faculty of Physical Sciences

University of Iceland

Research output: Contribution to journal › Article › peer-review

Abstract

Put a number on it: Absolute cross-sections for dissociative electron attachment (DEA) to the common precursor molecule cobalt tricarbonyl nitrosyl in the gas phase are reported (see scheme, Co dark blue, O red, C gray, N light blue) along with the branching ratios for the negative ions and the electron affinities for the neutral radical fragments. Further, a general mechanism of DEA is proposed for metal-carbonyl compounds.

Original language	English
Pages (from-to)	9475-9477
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	40
DOIs	https://doi.org/10.1002/anie.201103234
Publication status	Published - 26 Sept 2011

Other keywords

carbonyl ligands
cobalt
cross-sections
dissociative electron attachment
gas-phase reactions

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abstract = "Put a number on it: Absolute cross-sections for dissociative electron attachment (DEA) to the common precursor molecule cobalt tricarbonyl nitrosyl in the gas phase are reported (see scheme, Co dark blue, O red, C gray, N light blue) along with the branching ratios for the negative ions and the electron affinities for the neutral radical fragments. Further, a general mechanism of DEA is proposed for metal-carbonyl compounds.",

keywords = "carbonyl ligands, cobalt, cross-sections, dissociative electron attachment, gas-phase reactions",

author = "Sarah Engmann and Michal Stano and {\v S}tefan Matej{\v c}{\'i}k and Oddur Ing{\'o}lfsson",

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AU - Ingólfsson, Oddur

PY - 2011/9/26

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N2 - Put a number on it: Absolute cross-sections for dissociative electron attachment (DEA) to the common precursor molecule cobalt tricarbonyl nitrosyl in the gas phase are reported (see scheme, Co dark blue, O red, C gray, N light blue) along with the branching ratios for the negative ions and the electron affinities for the neutral radical fragments. Further, a general mechanism of DEA is proposed for metal-carbonyl compounds.

AB - Put a number on it: Absolute cross-sections for dissociative electron attachment (DEA) to the common precursor molecule cobalt tricarbonyl nitrosyl in the gas phase are reported (see scheme, Co dark blue, O red, C gray, N light blue) along with the branching ratios for the negative ions and the electron affinities for the neutral radical fragments. Further, a general mechanism of DEA is proposed for metal-carbonyl compounds.

KW - carbonyl ligands

KW - cobalt

KW - cross-sections

KW - dissociative electron attachment

KW - gas-phase reactions

UR - https://www.scopus.com/pages/publications/80053138368

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M3 - Article

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ER -

The role of dissociative electron attachment in focused electron beam induced processing: A case study on cobalt tricarbonyl nitrosyl

Abstract

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