Three-photon absorption spectroscopy: The L(1Φ3) and m(3∏1) states of HCl and DCl

Ágúst Kvaran; Huasheng Wang

doi:10.1080/00268970210148787

Three-photon absorption spectroscopy: The L(¹Φ₃) and m(³∏₁) states of HCl and DCl

Ágúst Kvaran, Huasheng Wang

Faculty of Physical Sciences

University of Iceland

Research output: Contribution to journal › Article › peer-review

Abstract

Analysis of (3 + 1) REMPI room temperature spectra by use of three-photon absorption modelling allowed, for the first time, identification and characterization of Ω = 3, φ states (L(¹Φ₃)) in HCl and DCl and of the m(³∏₁) state in DCl. Simulation analyses and determination of isotope shifts allowed evaluation of vibrational and rotational spectroscopic parameters for both states and both molecules. The mechanism of three-photon absorption in the m(³∏₁) ← X(¹Σ⁺) transition is discussed.

Original language	English
Pages (from-to)	3513-3519
Number of pages	7
Journal	Molecular Physics
Volume	100
Issue number	22
DOIs	https://doi.org/10.1080/00268970210148787
Publication status	Published - 20 Nov 2002

Bibliographical note

Funding Information: The financial support of the University Research Fund, University of Iceland and the Icelandic Science Foundation is gratefully acknowledged. We would also like to thank Benedikt G. Waage and J6n Matthiasson for useful help with this project.

Access to Document

10.1080/00268970210148787

Cite this

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title = "Three-photon absorption spectroscopy: The L(1Φ3) and m(3∏1) states of HCl and DCl",

abstract = "Analysis of (3 + 1) REMPI room temperature spectra by use of three-photon absorption modelling allowed, for the first time, identification and characterization of Ω = 3, φ states (L(1Φ3)) in HCl and DCl and of the m(3∏1) state in DCl. Simulation analyses and determination of isotope shifts allowed evaluation of vibrational and rotational spectroscopic parameters for both states and both molecules. The mechanism of three-photon absorption in the m(3∏1) ← X(1Σ+) transition is discussed.",

author = "{\'A}g{\'u}st Kvaran and Huasheng Wang",

note = "Funding Information: The financial support of the University Research Fund, University of Iceland and the Icelandic Science Foundation is gratefully acknowledged. We would also like to thank Benedikt G. Waage and J6n Matthiasson for useful help with this project.",

year = "2002",

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T2 - The L(1Φ3) and m(3∏1) states of HCl and DCl

AU - Kvaran, Ágúst

AU - Wang, Huasheng

N1 - Funding Information: The financial support of the University Research Fund, University of Iceland and the Icelandic Science Foundation is gratefully acknowledged. We would also like to thank Benedikt G. Waage and J6n Matthiasson for useful help with this project.

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Y1 - 2002/11/20

N2 - Analysis of (3 + 1) REMPI room temperature spectra by use of three-photon absorption modelling allowed, for the first time, identification and characterization of Ω = 3, φ states (L(1Φ3)) in HCl and DCl and of the m(3∏1) state in DCl. Simulation analyses and determination of isotope shifts allowed evaluation of vibrational and rotational spectroscopic parameters for both states and both molecules. The mechanism of three-photon absorption in the m(3∏1) ← X(1Σ+) transition is discussed.

AB - Analysis of (3 + 1) REMPI room temperature spectra by use of three-photon absorption modelling allowed, for the first time, identification and characterization of Ω = 3, φ states (L(1Φ3)) in HCl and DCl and of the m(3∏1) state in DCl. Simulation analyses and determination of isotope shifts allowed evaluation of vibrational and rotational spectroscopic parameters for both states and both molecules. The mechanism of three-photon absorption in the m(3∏1) ← X(1Σ+) transition is discussed.

UR - https://www.scopus.com/pages/publications/0037146215

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DO - 10.1080/00268970210148787

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